By Michael B. Smith
Compendium of natural man made tools keeps the incentive of the sequence, that's to facilitate the quest for caliber, chosen useful crew alterations, geared up via reacting sensible workforce of beginning fabric and useful crew shaped, with complete references to every response.
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Extra resources for General and Synthetic Methods Volume 10
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PARKES Synthesis of Aldehydes and Ketones Oxidative Methods. l have reported on the use of the cyclic chromate ester ( 1 ) as a catalyst for the peracetic acid oxidation of secondary alcohols. The reagent oxidises primary alcohols very slowly, and is compatible with tetrahydropyranyl protection of alcohols; furthermore, it has the great advantage of avoiding the toxicological and disposal problems associated with stoichiometric chromium reagents. The selective oxidation of benzylic alcohols in the presence of allylic alcohol functionality can be achieved in good yields by the use of Fremy's salt under phase-transfer conditions2.
S O C . , Chem. , 1985, 26, 203. T. Suzuki, H. Ohshima, and T. Fu jiwara, Chem. , 1985, 1249. , 1985, 26, 4923. Michelotti, J. Org. , 1985, 50, 1122. Runge, J. Org. , 1985, 50, 364 ; A. M. Caporusso, F. Lardicci, Tetrahedron Lett. Elsevier and P. Vermeer, J. Org. , 1985, 50, 3042. , 1985, 26, 4197. Spadaro, J. Chem. , Chem. , 1985, 157 1. Yamaguchi, J. Chem. , Chem. , 1985, 697. M. Ochiai , M. Kunishima, K. Sumi, Y. Nagao, E. Fu jita, M. Arimoto, and H. , 1985, 26, 4501. Surber, J. Am. Chem. , 1985, 107, 1452.