By J. S. Davies
This product isn't on hand individually, it's only offered as a part of a suite. There are 750 items within the set and those are all offered as one entity. summary: This product isn't to be had individually, it is just bought as a part of a suite. There are 750 items within the set and those are all offered as one entity
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Extra resources for Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC)) (Vol 27)
2) have been obtained by Lewis-acid catalysed ring-opening by indoles, of the aziridine (60). ~~~ cyclized tryptophan analogues formed with the a-amino group through an isoleucyl bridge270 are members of a family of conformationally constrained amino acids that includes potential protein kinase C modulators. 271 An efficient synthesis of 5 - a ~ i d o t r y p t o p h a nemploys ~~~ a standard route, starting from 5-nitroindole. 13 Synthesis of a-Amino Acids Carrying Sulfur- or Selenium-containing Side Chains - This class of amino acid is gaining further importance, since certain sulfur functional groups react with nitric oxide.
17 Resolution of DL-Amino Acids - Active development of existing methodology, especially in topic areas under the heading of chromatographic resolution, would be an accurate description of current research. Analytical aspects (determination of enantiomer ratios by chromatographic and related means) are mostly covered in Section 7, and configurational assignments achieved through synthesis strategies are covered in earlier Sections. Marfey’s ~~~ reagent can be used both to generate diastereoisomeric derivatives and to assign absolute configuration to individual enantiomers, for example to m i c r i ~ y s t i n sUse .
G. 15 Synthesis of Isotopically Labelled Amino Acids - All the familiar isotopes featured under this heading over the years are represented in the current literature. 2H-Labelled protein amino acids, intended to assist biosynthetic studies, often call for the most ingenious synthetic strategies, as illustrated by (2S,4S)- and (2S,4R)-[5,5,5-2H3]1eucine. 286 Synthesis of labelled D-(prop-2yny1)glycine (70) follows an identical strategy using a carbanion as n ~ c l e o p h i l e . 288 The development of established methods (see Vol.